dor_id: 4128865

506.#.#.a: Público

590.#.#.d: Los artículos enviados a la "Revista Internacional de Contaminación Ambiental" se juzgan por medio de un proceso de revisión por pares

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650.#.4.x: Biología y Química

336.#.#.b: article

336.#.#.3: Artículo de Investigación

336.#.#.a: Artículo

351.#.#.6: https://www.revistascca.unam.mx/rica/index.php/rica/index

351.#.#.b: Revista Internacional de Contaminación Ambiental

351.#.#.a: Artículos

harvesting_group: RevistasUNAM

270.1.#.p: Revistas UNAM. Dirección General de Publicaciones y Fomento Editorial, UNAM en revistas@unam.mx

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270.#.#.d: MX

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850.#.#.a: Universidad Nacional Autónoma de México

856.4.0.u: https://www.revistascca.unam.mx/rica/index.php/rica/article/view/53820/47092

100.1.#.a: Antaño López, René; Hernández Pérez, Fidel; Espejel Ayala, Fabricio

524.#.#.a: Antaño López, René, et al. (2021). THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST. Revista Internacional de Contaminación Ambiental; Vol. 37, 2021; 501-512. Recuperado de https://repositorio.unam.mx/contenidos/4128865

245.1.0.a: THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Instituto de Ciencias de la Atmósfera y Cambio Climático, UNAM

264.#.0.c: 2021

264.#.1.c: 2021-08-04

653.#.#.a: vanadium; industrial wastes; spent catalyst; electrochemical processes; Pourbaix diagrams; zeolites; vanadium; industrial wastes; spent catalyst; electrochemical processes; Pourbaix diagrams; zeolites

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC 4.0 Internacional, https://creativecommons.org/licenses/by-nc/4.0/legalcode.es, para un uso diferente consultar al responsable jurídico del repositorio por medio del correo electrónico claudio.amescua@atmosfera.unam.mx

884.#.#.k: https://www.revistascca.unam.mx/rica/index.php/rica/article/view/53820

001.#.#.#: 105.oai:ojs.pkp.sfu.ca:article/53820

041.#.7.h: eng

520.3.#.a: Due to the low abundance of vanadium in nature (about 135 g/t), the feasibility to recover it from industrial wastes has highly attracted scientific and technological attention. The main recovery routes reported are associated with chemical or thermochemical processes. However, the electrochemical recovery of vanadium from industrial wastes has been poorly investigated. In this work, a thermodynamic and electrochemical study for the possible vanadium recovery from a spent catalyst generated in the petrochemical industry was conducted. The study was divided into two stages using low vanadium concentrations. In the first stage, the recovery of vanadium was possible in its V4+ state at low reduction potentials, whereas for the second stage, cyclic voltammetry was used to calculate the diffusion coefficient and the heterogeneous velocity coefficient of the V5+/V4+ redox pair. The obtained values are similar to those reported in the literature for aqueous solutions at high vanadium concentrations and would allow the design of the system at large scale. This report aims to set the conditions for the possible vanadium recovery from a spent catalyst by means of electrochemical processes, although the optimization of such conditions must be further explored.

773.1.#.t: Revista Internacional de Contaminación Ambiental; Vol. 37 (2021); 501-512

773.1.#.o: https://www.revistascca.unam.mx/rica/index.php/rica/index

022.#.#.a: ISSN impreso: 0188-4999

310.#.#.a: Trimestral

300.#.#.a: Páginas: 501-512

264.#.1.b: Instituto de Ciencias de la Atmósfera y Cambio Climático, UNAM

doi: https://doi.org/10.20937/RICA.53820

harvesting_date: 2023-11-08 13:10:00.0

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245.1.0.b: THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST

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license_url: https://creativecommons.org/licenses/by-nc/4.0/legalcode.es

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Artículo

THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST

Antaño López, René; Hernández Pérez, Fidel; Espejel Ayala, Fabricio

Instituto de Ciencias de la Atmósfera y Cambio Climático, UNAM, publicado en Revista Internacional de Contaminación Ambiental, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Cita

Antaño López, René, et al. (2021). THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST. Revista Internacional de Contaminación Ambiental; Vol. 37, 2021; 501-512. Recuperado de https://repositorio.unam.mx/contenidos/4128865

Descripción del recurso

Autor(es)
Antaño López, René; Hernández Pérez, Fidel; Espejel Ayala, Fabricio
Tipo
Artículo de Investigación
Área del conocimiento
Biología y Química
Título
THERMODYNAMIC AND ELECTROCHEMICAL STUDY OF VANADIUM SOLUTIONS: TOWARDS VANADIUM RECOVERY FROM A SPENT CATALYST
Fecha
2021-08-04
Resumen
Due to the low abundance of vanadium in nature (about 135 g/t), the feasibility to recover it from industrial wastes has highly attracted scientific and technological attention. The main recovery routes reported are associated with chemical or thermochemical processes. However, the electrochemical recovery of vanadium from industrial wastes has been poorly investigated. In this work, a thermodynamic and electrochemical study for the possible vanadium recovery from a spent catalyst generated in the petrochemical industry was conducted. The study was divided into two stages using low vanadium concentrations. In the first stage, the recovery of vanadium was possible in its V4+ state at low reduction potentials, whereas for the second stage, cyclic voltammetry was used to calculate the diffusion coefficient and the heterogeneous velocity coefficient of the V5+/V4+ redox pair. The obtained values are similar to those reported in the literature for aqueous solutions at high vanadium concentrations and would allow the design of the system at large scale. This report aims to set the conditions for the possible vanadium recovery from a spent catalyst by means of electrochemical processes, although the optimization of such conditions must be further explored.
Tema
vanadium; industrial wastes; spent catalyst; electrochemical processes; Pourbaix diagrams; zeolites; vanadium; industrial wastes; spent catalyst; electrochemical processes; Pourbaix diagrams; zeolites
Idioma
eng
ISSN
ISSN impreso: 0188-4999

Enlaces