dor_id: 4110195

506.#.#.a: Público

590.#.#.d: Los artículos enviados a la revista "Journal of Applied Research and Technology", se juzgan por medio de un proceso de revisión por pares

510.0.#.a: Scopus, Directory of Open Access Journals (DOAJ); Sistema Regional de Información en Línea para Revistas Científicas de América Latina, el Caribe, España y Portugal (Latindex); Indice de Revistas Latinoamericanas en Ciencias (Periódica); La Red de Revistas Científicas de América Latina y el Caribe, España y Portugal (Redalyc); Consejo Nacional de Ciencia y Tecnología (CONACyT); Google Scholar Citation

561.#.#.u: https://www.icat.unam.mx/

650.#.4.x: Ingenierías

336.#.#.b: article

336.#.#.3: Artículo de Investigación

336.#.#.a: Artículo

351.#.#.6: https://jart.icat.unam.mx/index.php/jart

351.#.#.b: Journal of Applied Research and Technology

351.#.#.a: Artículos

harvesting_group: RevistasUNAM

270.1.#.p: Revistas UNAM. Dirección General de Publicaciones y Fomento Editorial, UNAM en revistas@unam.mx

590.#.#.c: Open Journal Systems (OJS)

270.#.#.d: MX

270.1.#.d: México

590.#.#.b: Concentrador

883.#.#.u: https://revistas.unam.mx/catalogo/

883.#.#.a: Revistas UNAM

590.#.#.a: Coordinación de Difusión Cultural

883.#.#.1: https://www.publicaciones.unam.mx/

883.#.#.q: Dirección General de Publicaciones y Fomento Editorial

850.#.#.a: Universidad Nacional Autónoma de México

856.4.0.u: https://jart.icat.unam.mx/index.php/jart/article/view/748/711

100.1.#.a: Ruiz, Misael García; Pliego, Julia Aguilar; Franco, Luis E. Noreña; Álvarez, Carlos Márquez; Pariente, Joaquín Pérez; Guaregua, Nancy C. M artin

524.#.#.a: Ruiz, Misael García, et al. (2018). Synthesis and characterization of a mesoporous cerium oxide catalyst for the conversion of glycerol. Journal of Applied Research and Technology; Vol. 16 Núm. 6. Recuperado de https://repositorio.unam.mx/contenidos/4110195

245.1.0.a: Synthesis and characterization of a mesoporous cerium oxide catalyst for the conversion of glycerol

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Instituto de Ciencias Aplicadas y Tecnología, UNAM

264.#.0.c: 2018

264.#.1.c: 2019-06-29

653.#.#.a: Mesoporous Ce02; glycerol; acetol; dehydration

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-SA 4.0 Internacional, https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es, para un uso diferente consultar al responsable jurídico del repositorio por medio del correo electrónico gabriel.ascanio@icat.unam.mx

884.#.#.k: https://jart.icat.unam.mx/index.php/jart/article/view/748

001.#.#.#: 074.oai:ojs2.localhost:article/748

041.#.7.h: eng

520.3.#.a: CeO2 mesoporous materials were synthesized employing the “hard and soft template” technique. Ceria catalysts have been prepared by a nanocasting procedure using SBA-15 and KIT-6 silica-based templates and Pluronic P123 and F127 for the “soft template” technique. The mesoporous CeO2 was characterized by techniques such as N2 physisorption, which confirmed a mesoporous size pore system and transmission electron microscopy, TEM, which confirmed the material ordered pore structure. TGA/DTA analysis was used to determine the loss of weight compared to the temperature before and after the elimination of the template. On the other hand, by means of IR spectroscopy of the Ce-KIT-6 material, the partial elimination of the Si template after the NaOH treatment was confirmed by decreasing the peaks corresponding to the vibration bands of the Si-O-Si linkages. Finally, by temperature-programmed desorption (TPD) of NH3 and CO2, the acid and basic strength of the catalysts were determined, respectively. All samples exhibited much higher total basicity relative to total acidity. The analysis of TPR-H2 showed regions of low temperature (350-400ºC) where the reduction of the bulk is plausible to be initiated and of high temperature (550ºC) of superficial reduction of the ceria.The performance of the catalysts was evaluated in the dehydration reaction of glycerol in gas phase at 320 ºC. The mesoporous CeO2 material was selective to acetol and reached a 100% conversion of glycerol. The catalyst prepared by the “soft template” technique (CeO2-P123) was the most selective to acetol (76%) with a 12% selectivity to acrolein. With the catalyst prepared by the “hard template” technique (Ce-KIT-6), the selectivity towards acetol was 48% and 22% towards acrolein. The acid properties of CeO2 were found to be a determining factor for the selectivity to acetol and acrolein.

773.1.#.t: Journal of Applied Research and Technology; Vol. 16 Núm. 6

773.1.#.o: https://jart.icat.unam.mx/index.php/jart

022.#.#.a: ISSN electrónico: 2448-6736; ISSN: 1665-6423

310.#.#.a: Bimestral

264.#.1.b: Instituto de Ciencias Aplicadas y Tecnología, UNAM

doi: https://doi.org/10.22201/icat.16656423.2018.16.6.748

harvesting_date: 2023-11-08 13:10:00.0

856.#.0.q: application/pdf

file_creation_date: 2019-11-12 19:24:27.0

file_modification_date: 2019-11-12 19:24:27.0

file_creator: Mónica Aparicio Estrada

file_name: fee4ad23dfc7698e74a2b50d8b75ee5e6d10117022ea08e3c3f828e698c7bccd.pdf

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last_modified: 2024-03-19 14:00:00

license_url: https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es

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