dor_id: 4108441

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650.#.4.x: Físico Matemáticas y Ciencias de la Tierra

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351.#.#.a: Artículos

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856.4.0.u: https://rmf.smf.mx/ojs/rmf/article/view/Vol.%2065%2C%20issue%205%2C%20pp.%20440-448/4693; https://rmf.smf.mx/ojs/rmf/article/downloadSuppFile/Vol.%2065%2C%20issue%205%2C%20pp.%20440-448/597

100.1.#.a: Martino, L. J.; D’Angelo, C. A.; Rodríguez, C. I.; Díaz Pace, D. M.

100.1.#.u: CONICET; CICPBA.

524.#.#.a: Martino, L. J., et al. (2019). Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy. Revista Mexicana de Física; Vol 65, No 5 Sept-Oct: 440-448. Recuperado de https://repositorio.unam.mx/contenidos/4108441

245.1.0.a: Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Facultad de Ciencias, UNAM

264.#.0.c: 2019

264.#.1.c: 2019-09-02

653.#.#.a: Fluvial sediments; chromium; copper; laser–induced breakdown spectroscopy

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-ND 4.0 Internacional, https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es, fecha de asignación de la licencia 2019-09-02, para un uso diferente consultar al responsable jurídico del repositorio por medio de rmf@ciencias.unam.mx

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001.#.#.#: oai:ojs.rmf.smf.mx:article/4293

041.#.7.h: eng

520.3.#.a: In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis,different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated.High values of the correlation coefficients of calibration ( R c 2 = 0 : 984 for Cr; R c 2 = 0 : 986 for Cu) and cross-validation ( R cv 2 = 0 : 985 for Cr; R cv 2 = 0 : 981 for Cu) were obtained.The calculated limits of detection ( LoD ) were 2.9 p± for Cr and 3.3 p± for Cu, and the limits of quantification ( LoQ ) were 9.5 p± for Cr and 11 p± for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 p±, Cu: 81 p±) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.

773.1.#.t: Revista Mexicana de Física; Vol 65, No 5 Sept-Oct (2019): 440-448

773.1.#.o: https://rmf.smf.mx/ojs/rmf/index

046.#.#.j: 2020-11-25 00:00:00.000000

022.#.#.a: 2683-2224 (digital); 0035-001X (impresa)

310.#.#.a: Bimestral

264.#.1.b: Sociedad Mexicana de Física, A.C.

758.#.#.1: https://rmf.smf.mx/ojs/rmf/index

doi: https://doi.org/10.31349/RevMexFis.65.440

handle: 008b5a8190d1825b

harvesting_date: 2020-09-23 00:00:00.0

856.#.0.q: application/pdf

last_modified: 2020-11-27 00:00:00

license_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es

license_type: by-nc-nd

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Artículo

Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy

Martino, L. J.; D’Angelo, C. A.; Rodríguez, C. I.; Díaz Pace, D. M.

Facultad de Ciencias, UNAM, publicado en Revista Mexicana de Física, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Entidad o dependencia
Facultad de Ciencias, UNAM
Revista
Repositorio
Contacto
Revistas UNAM. Dirección General de Publicaciones y Fomento Editorial, UNAM en revistas@unam.mx

Cita

Martino, L. J., et al. (2019). Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy. Revista Mexicana de Física; Vol 65, No 5 Sept-Oct: 440-448. Recuperado de https://repositorio.unam.mx/contenidos/4108441

Descripción del recurso

Autor(es)
Martino, L. J.; D’Angelo, C. A.; Rodríguez, C. I.; Díaz Pace, D. M.
Adscripción del autor
CONICET; CICPBA.
Tipo
Artículo de Investigación
Área del conocimiento
Físico Matemáticas y Ciencias de la Tierra
Título
Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy
Fecha
2019-09-02
Resumen
In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis,different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated.High values of the correlation coefficients of calibration ( R c 2 = 0 : 984 for Cr; R c 2 = 0 : 986 for Cu) and cross-validation ( R cv 2 = 0 : 985 for Cr; R cv 2 = 0 : 981 for Cu) were obtained.The calculated limits of detection ( LoD ) were 2.9 p± for Cr and 3.3 p± for Cu, and the limits of quantification ( LoQ ) were 9.5 p± for Cr and 11 p± for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 p±, Cu: 81 p±) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.
Tema
Fluvial sediments; chromium; copper; laser–induced breakdown spectroscopy
Idioma
eng
ISSN
2683-2224 (digital); 0035-001X (impresa)

Enlaces