dor_id: 4108441
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561.#.#.u: http://www.fciencias.unam.mx/
650.#.4.x: Físico Matemáticas y Ciencias de la Tierra
336.#.#.b: info:eu-repo/semantics/article
336.#.#.3: Artículo de Investigación
336.#.#.a: Artículo
351.#.#.6: https://rmf.smf.mx/ojs/rmf/index
351.#.#.b: Revista Mexicana de Física
351.#.#.a: Artículos
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270.#.#.d: MX
270.1.#.d: México
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590.#.#.a: Coordinación de Difusión Cultural
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883.#.#.q: Dirección General de Publicaciones y Fomento Editorial, UNAM
850.#.#.a: Universidad Nacional Autónoma de México
856.4.0.u: https://rmf.smf.mx/ojs/rmf/article/view/Vol.%2065%2C%20issue%205%2C%20pp.%20440-448/4693; https://rmf.smf.mx/ojs/rmf/article/downloadSuppFile/Vol.%2065%2C%20issue%205%2C%20pp.%20440-448/597
100.1.#.a: Martino, L. J.; D’Angelo, C. A.; Rodríguez, C. I.; Díaz Pace, D. M.
100.1.#.u: CONICET; CICPBA.
524.#.#.a: Martino, L. J., et al. (2019). Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy. Revista Mexicana de Física; Vol 65, No 5 Sept-Oct: 440-448. Recuperado de https://repositorio.unam.mx/contenidos/4108441
245.1.0.a: Rapid monitoring of heavy metals in fluvial sediments using laser–induced breakdown spectroscopy
502.#.#.c: Universidad Nacional Autónoma de México
561.1.#.a: Facultad de Ciencias, UNAM
264.#.0.c: 2019
264.#.1.c: 2019-09-02
653.#.#.a: Fluvial sediments; chromium; copper; laser–induced breakdown spectroscopy
506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-ND 4.0 Internacional, https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es, fecha de asignación de la licencia 2019-09-02, para un uso diferente consultar al responsable jurídico del repositorio por medio de rmf@ciencias.unam.mx
884.#.#.k: https://rmf.smf.mx/ojs/rmf/article/view/Vol.%2065%2C%20issue%205%2C%20pp.%20440-448
001.#.#.#: oai:ojs.rmf.smf.mx:article/4293
041.#.7.h: eng
520.3.#.a: In this work, a quantitative analysis of heavy metals Cr and Cu in fluvial sediments was carried out by Laser-induced breakdown Spectroscopy (LIBS) to assess the anthropogenic. To perform the analysis,different sediment samples were collected at selected positions. Standard addition calibration curves were constructed for Cr and Cu by measuring the Cr I line at 357.87 nm and Cu I line at 324.75 nm. The moisture and organic matter contents of the sediments were taken into account to overcome the matrix effect. The quantitative models were evaluated statistically to evaluate the robustness and prediction ability of the method. Low values for root-mean-square errors for calibration (RMSEC), prediction (RMSEP) and cross-validation (RMSECV) were calculated.High values of the correlation coefficients of calibration ( R c 2 = 0 : 984 for Cr; R c 2 = 0 : 986 for Cu) and cross-validation ( R cv 2 = 0 : 985 for Cr; R cv 2 = 0 : 981 for Cu) were obtained.The calculated limits of detection ( LoD ) were 2.9 p± for Cr and 3.3 p± for Cu, and the limits of quantification ( LoQ ) were 9.5 p± for Cr and 11 p± for Cu. Concentrations of Cr and Cu higher than the baseline values were obtained in the sediments downstream (Cr: 49 p±, Cu: 81 p±) which are indicative of the pollution of the basin by heavy metals due to the spill of untreated effluents derived from anthropogenic activities. LIBS analysis was optimized for reliable heavy metal monitoring in fluvial sediments.
773.1.#.t: Revista Mexicana de Física; Vol 65, No 5 Sept-Oct (2019): 440-448
773.1.#.o: https://rmf.smf.mx/ojs/rmf/index
046.#.#.j: 2020-11-25 00:00:00.000000
022.#.#.a: 2683-2224 (digital); 0035-001X (impresa)
310.#.#.a: Bimestral
264.#.1.b: Sociedad Mexicana de Física, A.C.
758.#.#.1: https://rmf.smf.mx/ojs/rmf/index
doi: https://doi.org/10.31349/RevMexFis.65.440
handle: 008b5a8190d1825b
harvesting_date: 2020-09-23 00:00:00.0
856.#.0.q: application/pdf
last_modified: 2020-11-27 00:00:00
license_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es
license_type: by-nc-nd
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