dor_id: 4142987

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336.#.#.b: article

336.#.#.3: Artículo de Investigación

336.#.#.a: Artículo

351.#.#.6: https://jart.icat.unam.mx/index.php/jart

351.#.#.b: Journal of Applied Research and Technology

351.#.#.a: Artículos

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270.1.#.p: Revistas UNAM. Dirección General de Publicaciones y Fomento Editorial, UNAM en revistas@unam.mx

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850.#.#.a: Universidad Nacional Autónoma de México

856.4.0.u: https://jart.icat.unam.mx/index.php/jart/article/view/955/942

100.1.#.a: Hermanto, D.; Siswanta, D.; Mudasir, M.; Muhali, M.; Ismillayli, N.

524.#.#.a: Hermanto, D., et al. (2022). Design and Synthesis of the Poly Vinyl Chloride (PVC) Membrane for Fe(III) Ion Selective Electrode (ISE) Based on Ester Modified Humic Acid (EHA) as an Ionophore. Journal of Applied Research and Technology; Vol. 20 Núm. 6, 2022; 630-637. Recuperado de https://repositorio.unam.mx/contenidos/4142987

245.1.0.a: Design and Synthesis of the Poly Vinyl Chloride (PVC) Membrane for Fe(III) Ion Selective Electrode (ISE) Based on Ester Modified Humic Acid (EHA) as an Ionophore

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Instituto de Ciencias Aplicadas y Tecnología, UNAM

264.#.0.c: 2022

264.#.1.c: 2022-12-23

653.#.#.a: PVC membrane; Fe(III); ion selective electrode; ester modified humic acid

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-SA 4.0 Internacional, https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es, para un uso diferente consultar al responsable jurídico del repositorio por medio del correo electrónico gabriel.ascanio@icat.unam.mx

884.#.#.k: https://jart.icat.unam.mx/index.php/jart/article/view/955

001.#.#.#: 074.oai:ojs2.localhost:article/955

041.#.7.h: eng

520.3.#.a: Design and synthesis of the poly vinyl chloride (PVC) membrane as Fe(III) ion selective electrode (ISE) sensor based on EHA ionophore as an excellent sensory molecule for monitoring Fe(III) in the sample solution had been done. Simple and efficient EHA was made by condensation of carboxylic acid HA with ethanol and sulfuric acid as catalist. PVC membrane was prepared by mixed all component such as PVC powder, EHA, plasticizer (o-NPOE and DOP) and anion lipophilic (Sodium-TPB and oleic acid) with a total weight of 100 mg and dissolved in 1 mL of dry THF. The electrode membrane responses showed that the electrodes were highly selective to ion Fe3+ at pH 3 with response time of ±50 seconds. The dynamic range of the membrane ISE sensor was 10-1–10-7 M with the value of Nernst factor was ±19 mV per decade. The membrane electrode can be used for at least 5 weeks. The analytical results of Fe(III) measurement showed good confirmity with reference method (AAS), suggesting that the developed analytical tool could be used to measure and monitor Fe(III) in the real water samples.

773.1.#.t: Journal of Applied Research and Technology; Vol. 20 Núm. 6 (2022); 630-637

773.1.#.o: https://jart.icat.unam.mx/index.php/jart

022.#.#.a: ISSN electrónico: 2448-6736; ISSN: 1665-6423

310.#.#.a: Bimestral

300.#.#.a: Páginas: 630-637

264.#.1.b: Instituto de Ciencias Aplicadas y Tecnología, UNAM

doi: https://doi.org/10.22201/icat.24486736e.2022.20.6.955

harvesting_date: 2023-11-08 13:10:00.0

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file_creator: Yolanda G.G.

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Artículo

Design and Synthesis of the Poly Vinyl Chloride (PVC) Membrane for Fe(III) Ion Selective Electrode (ISE) Based on Ester Modified Humic Acid (EHA) as an Ionophore

Hermanto, D.; Siswanta, D.; Mudasir, M.; Muhali, M.; Ismillayli, N.

Instituto de Ciencias Aplicadas y Tecnología, UNAM, publicado en Journal of Applied Research and Technology, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Cita

Hermanto, D., et al. (2022). Design and Synthesis of the Poly Vinyl Chloride (PVC) Membrane for Fe(III) Ion Selective Electrode (ISE) Based on Ester Modified Humic Acid (EHA) as an Ionophore. Journal of Applied Research and Technology; Vol. 20 Núm. 6, 2022; 630-637. Recuperado de https://repositorio.unam.mx/contenidos/4142987

Descripción del recurso

Autor(es)
Hermanto, D.; Siswanta, D.; Mudasir, M.; Muhali, M.; Ismillayli, N.
Tipo
Artículo de Investigación
Área del conocimiento
Ingenierías
Título
Design and Synthesis of the Poly Vinyl Chloride (PVC) Membrane for Fe(III) Ion Selective Electrode (ISE) Based on Ester Modified Humic Acid (EHA) as an Ionophore
Fecha
2022-12-23
Resumen
Design and synthesis of the poly vinyl chloride (PVC) membrane as Fe(III) ion selective electrode (ISE) sensor based on EHA ionophore as an excellent sensory molecule for monitoring Fe(III) in the sample solution had been done. Simple and efficient EHA was made by condensation of carboxylic acid HA with ethanol and sulfuric acid as catalist. PVC membrane was prepared by mixed all component such as PVC powder, EHA, plasticizer (o-NPOE and DOP) and anion lipophilic (Sodium-TPB and oleic acid) with a total weight of 100 mg and dissolved in 1 mL of dry THF. The electrode membrane responses showed that the electrodes were highly selective to ion Fe3+ at pH 3 with response time of ±50 seconds. The dynamic range of the membrane ISE sensor was 10-1–10-7 M with the value of Nernst factor was ±19 mV per decade. The membrane electrode can be used for at least 5 weeks. The analytical results of Fe(III) measurement showed good confirmity with reference method (AAS), suggesting that the developed analytical tool could be used to measure and monitor Fe(III) in the real water samples.
Tema
PVC membrane; Fe(III); ion selective electrode; ester modified humic acid
Idioma
eng
ISSN
ISSN electrónico: 2448-6736; ISSN: 1665-6423

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