dor_id: 45881

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351.#.#.b: Journal of Applied Research and Technology

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856.4.0.u: https://jart.icat.unam.mx/index.php/jart/article/view/17/17

100.1.#.a: Zhang, Yu ling; Zhao, Cai xia; Liu, Xiao dong; Li, Wei; Wang, Jiao long; Hu, Zhi guang

524.#.#.a: Zhang, Yu ling, et al. (2016). Application of poly(aspartic acid-citric acid) copolymer compound inhibitoras an effective and environmental agent against calcium phosphate in coolingwater systems. Journal of Applied Research and Technology; Vol. 14 Núm. 6. Recuperado de https://repositorio.unam.mx/contenidos/45881

245.1.0.a: Application of poly(aspartic acid-citric acid) copolymer compound inhibitoras an effective and environmental agent against calcium phosphate in coolingwater systems

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Instituto de Ciencias Aplicadas y Tecnología, UNAM

264.#.0.c: 2016

264.#.1.c: 2016-12-01

653.#.#.a: Poly(aspartic acid-citric acid) copolymer (PAC); Polymaleic acid (HPMA); Compound inhibitor (PAC-HPMA); Calcium phosphate; Inhibition rate

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-SA 4.0 Internacional, https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es, para un uso diferente consultar al responsable jurídico del repositorio por medio del correo electrónico gabriel.ascanio@icat.unam.mx

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041.#.7.h: eng

520.3.#.a: Poly(aspartic acid-citric acid) copolymer (PAC) is a new product of poly(carboxylic acid) scale inhibitor. The study aims to develop a “green” water treatment agent for calcium phosphate scale. The article compares the efficiency of three polymeric antiscalants, poly(aspartic acid-citric acid) copolymer (PAC), polymaleic acid (HPMA) and a compound inhibitor (PAC-HPMA), for calcium phosphate scale prevention under varying experimental conditions. Inhibitor concentration, calcium concentration, system pH, temperature and experimental time were varied to determine their influences on inhibitor performance by the static scale inhibition method. The copolymer (PAC) was characterized by FTIR,1H NMR and 13C NMR. The compound inhibitor was applied in the actual circulating cooling water system. An atomic force microscope (AFM), X-ray powder diffraction (XRD) and a scale formation process analysis were used to explore the scale inhibition mechanism. The results showed that scale inhibition rates of PAC, HPMA and PAC-HPMA against Ca3(PO4)2were, respectively, about 23%, 41.5% and 63% when the dosage was 8 mg/L in the experiment. The compound inhibitor showed the better inhibition performance than the above two kinds of monomers. Under the actual working conditions, the inhibition rate of compound inhibitor was close to 100% and completely met the actual application requirements of scale inhibitor in circulating cooling water systems. The main inhibition mechanism was the decomposition-chelation dispersion effect. The compound inhibitor can be used as an efficient “green” scale inhibitor for calcium phosphate.

773.1.#.t: Journal of Applied Research and Technology; Vol. 14 Núm. 6

773.1.#.o: https://jart.icat.unam.mx/index.php/jart

022.#.#.a: ISSN electrónico: 2448-6736; ISSN: 1665-6423

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264.#.1.b: Instituto de Ciencias Aplicadas y Tecnología, UNAM

doi: https://doi.org/10.1016/j.jart.2016.08.006

harvesting_date: 2023-11-08 13:10:00.0

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Artículo

Application of poly(aspartic acid-citric acid) copolymer compound inhibitoras an effective and environmental agent against calcium phosphate in coolingwater systems

Zhang, Yu ling; Zhao, Cai xia; Liu, Xiao dong; Li, Wei; Wang, Jiao long; Hu, Zhi guang

Instituto de Ciencias Aplicadas y Tecnología, UNAM, publicado en Journal of Applied Research and Technology, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Cita

Zhang, Yu ling, et al. (2016). Application of poly(aspartic acid-citric acid) copolymer compound inhibitoras an effective and environmental agent against calcium phosphate in coolingwater systems. Journal of Applied Research and Technology; Vol. 14 Núm. 6. Recuperado de https://repositorio.unam.mx/contenidos/45881

Descripción del recurso

Autor(es)
Zhang, Yu ling; Zhao, Cai xia; Liu, Xiao dong; Li, Wei; Wang, Jiao long; Hu, Zhi guang
Tipo
Artículo de Investigación
Área del conocimiento
Ingenierías
Título
Application of poly(aspartic acid-citric acid) copolymer compound inhibitoras an effective and environmental agent against calcium phosphate in coolingwater systems
Fecha
2016-12-01
Resumen
Poly(aspartic acid-citric acid) copolymer (PAC) is a new product of poly(carboxylic acid) scale inhibitor. The study aims to develop a “green” water treatment agent for calcium phosphate scale. The article compares the efficiency of three polymeric antiscalants, poly(aspartic acid-citric acid) copolymer (PAC), polymaleic acid (HPMA) and a compound inhibitor (PAC-HPMA), for calcium phosphate scale prevention under varying experimental conditions. Inhibitor concentration, calcium concentration, system pH, temperature and experimental time were varied to determine their influences on inhibitor performance by the static scale inhibition method. The copolymer (PAC) was characterized by FTIR,1H NMR and 13C NMR. The compound inhibitor was applied in the actual circulating cooling water system. An atomic force microscope (AFM), X-ray powder diffraction (XRD) and a scale formation process analysis were used to explore the scale inhibition mechanism. The results showed that scale inhibition rates of PAC, HPMA and PAC-HPMA against Ca3(PO4)2were, respectively, about 23%, 41.5% and 63% when the dosage was 8 mg/L in the experiment. The compound inhibitor showed the better inhibition performance than the above two kinds of monomers. Under the actual working conditions, the inhibition rate of compound inhibitor was close to 100% and completely met the actual application requirements of scale inhibitor in circulating cooling water systems. The main inhibition mechanism was the decomposition-chelation dispersion effect. The compound inhibitor can be used as an efficient “green” scale inhibitor for calcium phosphate.
Tema
Poly(aspartic acid-citric acid) copolymer (PAC); Polymaleic acid (HPMA); Compound inhibitor (PAC-HPMA); Calcium phosphate; Inhibition rate
Idioma
eng
ISSN
ISSN electrónico: 2448-6736; ISSN: 1665-6423

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