dor_id: 45571

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856.4.0.u: https://jart.icat.unam.mx/index.php/jart/article/view/360/357

100.1.#.a: Farhoodi, M.; Mousavi, S. M.; Sotudeh Gharebagh, R.; Emam Djomeh, Z.; Oromiehie, A.; Mansour, H.

524.#.#.a: Farhoodi, M., et al. (2012). A Study on Physical Aging of Semicrystalline Polyethylene Terephthalate below the Glass Transition Point. Journal of Applied Research and Technology; Vol. 10 Núm. 5. Recuperado de https://repositorio.unam.mx/contenidos/45571

245.1.0.a: A Study on Physical Aging of Semicrystalline Polyethylene Terephthalate below the Glass Transition Point

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Instituto de Ciencias Aplicadas y Tecnología, UNAM

264.#.0.c: 2012

264.#.1.c: 2012-10-01

653.#.#.a: Enthalpy Relaxation; Glass Transition; Endothermic Peak; Polyethylene Terephthalate; Crystallization

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-SA 4.0 Internacional, https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode.es, para un uso diferente consultar al responsable jurídico del repositorio por medio del correo electrónico gabriel.ascanio@icat.unam.mx

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041.#.7.h: spa

520.3.#.a: Physical aging of semicrystalline polyethylene terephthalate was studied using differential scanning calorimetry(DSC). PET samples with crystallinity content of 0.28 were aged at two different temperatures, 25 and 45°C. Thesamples were stored for several days and periodically tested using DSC method. The glass transition temperature forthe samples aged at 25°C was about 73-74°C, and the position and intensity of endothermic peaks wereapproximately constant. Higher glass transition of the samples aged at 45°C, 73-86°C, was attributed to the enthalpyrelaxation process of amorphous regions of semicrystalline PET. For the samples aged at 45°C, the endothermicpeaks shifted to higher temperatures with increasing aging time. The position of the endothermic peaks determined bythe temperature of the maximum, Tmax, tended to increase with aging time for samples aged at 45°C, and theintensity of the peaks continuously increased with time; however, the results showed that the aging of PET samples at45°C even after 120 days continued the enthalpic relaxation of semicrystalline PET and that the process could bestudied by DSC method. The results also showed that the aging process could affect the final degree of crystallinity ofc-PET samples and the samples stored at 45°C showed higher degree of crystallinity than the samples aged at 25°C.

773.1.#.t: Journal of Applied Research and Technology; Vol. 10 Núm. 5

773.1.#.o: https://jart.icat.unam.mx/index.php/jart

022.#.#.a: ISSN electrónico: 2448-6736; ISSN: 1665-6423

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264.#.1.b: Instituto de Ciencias Aplicadas y Tecnología, UNAM

doi: https://doi.org/10.22201/icat.16656423.2012.10.5.360

harvesting_date: 2023-11-08 13:10:00.0

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last_modified: 2024-03-19 14:00:00

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Artículo

A Study on Physical Aging of Semicrystalline Polyethylene Terephthalate below the Glass Transition Point

Farhoodi, M.; Mousavi, S. M.; Sotudeh Gharebagh, R.; Emam Djomeh, Z.; Oromiehie, A.; Mansour, H.

Instituto de Ciencias Aplicadas y Tecnología, UNAM, publicado en Journal of Applied Research and Technology, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Cita

Farhoodi, M., et al. (2012). A Study on Physical Aging of Semicrystalline Polyethylene Terephthalate below the Glass Transition Point. Journal of Applied Research and Technology; Vol. 10 Núm. 5. Recuperado de https://repositorio.unam.mx/contenidos/45571

Descripción del recurso

Autor(es)
Farhoodi, M.; Mousavi, S. M.; Sotudeh Gharebagh, R.; Emam Djomeh, Z.; Oromiehie, A.; Mansour, H.
Tipo
Artículo de Investigación
Área del conocimiento
Ingenierías
Título
A Study on Physical Aging of Semicrystalline Polyethylene Terephthalate below the Glass Transition Point
Fecha
2012-10-01
Resumen
Physical aging of semicrystalline polyethylene terephthalate was studied using differential scanning calorimetry(DSC). PET samples with crystallinity content of 0.28 were aged at two different temperatures, 25 and 45°C. Thesamples were stored for several days and periodically tested using DSC method. The glass transition temperature forthe samples aged at 25°C was about 73-74°C, and the position and intensity of endothermic peaks wereapproximately constant. Higher glass transition of the samples aged at 45°C, 73-86°C, was attributed to the enthalpyrelaxation process of amorphous regions of semicrystalline PET. For the samples aged at 45°C, the endothermicpeaks shifted to higher temperatures with increasing aging time. The position of the endothermic peaks determined bythe temperature of the maximum, Tmax, tended to increase with aging time for samples aged at 45°C, and theintensity of the peaks continuously increased with time; however, the results showed that the aging of PET samples at45°C even after 120 days continued the enthalpic relaxation of semicrystalline PET and that the process could bestudied by DSC method. The results also showed that the aging process could affect the final degree of crystallinity ofc-PET samples and the samples stored at 45°C showed higher degree of crystallinity than the samples aged at 25°C.
Tema
Enthalpy Relaxation; Glass Transition; Endothermic Peak; Polyethylene Terephthalate; Crystallization
Idioma
spa
ISSN
ISSN electrónico: 2448-6736; ISSN: 1665-6423

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